I would do the way you have it listed. School name, then principal's name, etc. I figure that makes sure it gets to the correct building, then once inside...to the correct person.
Always work backwards, start big and get small (state, city, street, building, person) is what I was taught. I'm sure it will get there however you do it
Mr. Principal
ABC School
1234 Student Dr.
City, ST 112233